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Amides, coco, N,N-bis(hydroxyethyl)
 

Product Introduction: N,N-Bis(2-hydroxyethyl)cocamide (CAS: 68603-42-9)

Chemical Profile

N,N-Bis(2-hydroxyethyl)cocamide, with CAS number 68603-42-9, is a non-ionic surfactant derived from renewable coconut oil fatty acids and diethanolamine (DEA). It belongs to the ethanolamide family, characterized by a hydrophilic polyol headgroup (two hydroxyl groups per ethanolamine moiety) and a long-chain fatty acid tail (typically C12每C18, derived from coconut oil). This dual solubility profile (water-loving hydroxyls and oil-loving fatty acids) confers excellent surface activity, making it a versatile additive in formulations requiring emulsification, thickening, or foam stabilization.

Physical & Chemical Properties

  • Appearance: White to off-white waxy solid or soft paste (depending on purity; typical purity ≡98%).
  • Solubility: Readily dispersible in hot water, ethanol, and polar solvents (e.g., propylene glycol); partially soluble in mineral oils and non-polar solvents. Forms clear to translucent solutions in warm water.
  • Melting Point: 50每65∼C (solid grades); liquid fractions may remain fluid below 45∼C.
  • pH Value: Neutral to slightly basic (6.5每7.8 in 1% aqueous solution at 25∼C).
  • Viscosity: High viscosity in concentrated form (10,000每50,000 mPa﹞s at 25∼C); exhibits thixotropic behavior (shear-thinning) when agitated.
  • HLB Value: ~12每14 (indicating good emulsifying properties for O/W systems).

Key Applications

CAS 68603-42-9 is prized for its mildness, biodegradability, and multifunctionality, making it suitable for a wide range of industries:

  1. Personal Care Formulations

    • Hair Care: Acts as a foam booster and stabilizer in shampoos, body washes, and liquid soaps. Enhances lather volume and texture without harshness, improving user experience.
    • Skin Care: Serves as a mild emulsifier in creams, lotions, and facial cleansers, supporting the dispersion of oils and active ingredients while maintaining formulation stability.
    • Baby Care: Preferred for its low irritation potential, used in baby shampoos and body washes to ensure gentle cleansing.
  2. Household & Industrial Detergents

    • Laundry Detergents: Improves wetting, degreasing, and soil suspension, reducing cleaning time and enhancing stain removal efficiency.
    • Dishwashing Liquids: Stabilizes rich foam in high-alkaline formulations while preventing residue buildup.
    • Industrial Cleaners: Used in metal cleaners, floor cleaners, and car washes to improve grease cutting and surface wetting.
  3. Textile & Leather Processing

    • Textile Auxiliary: Functions as a softening agent and dye leveling agent, improving fabric softness, dye uptake, and color uniformity.
    • Leather Tanning: Enhances softness and water resistance in leather finishes, reducing stiffness and improving handle.

Safety & Compliance

  • Toxicity: Low acute toxicity. Oral LD₅₀ (rat) > 2500 mg/kg; dermal LD₅₀ (rabbit) > 5000 mg/kg. Non-irritating to skin (OECD 439 compliant) and eyes (OECD 492 compliant).
  • Regulatory Approvals:
    • REACH (EU): Registered (Article 10; CAS 68603-42-9 listed in ECHA database).
    • FDA (21 CFR 178.1010): Approved for indirect food contact applications (e.g., packaging adhesives).
    • EU Cosmetics Regulation (EC 1223/2009): Listed as a permitted surfactant (Annex VII, entry 140) for cosmetic use.
  • DEA Content: Manufactured with strict controls to minimize residual diethanolamine (<0.05%), aligning with strict safety guidelines for personal care and baby products.
  • Biodegradability: Readily biodegradable (>90% within 28 days, OECD 301B compliant), minimizing environmental impact.

Handling & Storage

  • Storage Conditions: Store in sealed, moisture-resistant containers at 10每30∼C. Avoid freezing or prolonged exposure to high temperatures (>40∼C), which may alter viscosity.
  • Shelf Life: 24 months from production date under recommended storage conditions.
  • Safety Precautions: Wear gloves and safety goggles during handling. Avoid inhalation of dust (for solid grades) or mist (for liquid grades). In case of skin contact, rinse thoroughly with water.
 
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